In the dry, 16PSI all round cold will lead to imbalances when hot (maybe 18 fronts, 22 rear, depending on circuit and how hard you push it). Tyre pressures should always be set hot for a circuit (it's how you use them). On the road the temp differences (and therefore pressure differences) are much smaller.
I missed the always oversteer when you fart on the throttle. I think you need to check rake, or as OBNS suggests, get it properly corner-weighted with a base setting.
As a reference, and I run track-only with AO48s, 140bhp and race suspension (Sigmax specification, which is Supersport spec with different tyres) I have:
1) Max castor - all washers are behind the wishbone
2) Neg 3 degrees camber
3) Some toe-out - about 0.5degrees out
4) c. 15mm rake
5) 20PSI hot all round; (23/25 in wet)
I change the roll bar settings for every circuit, but would start with something like:
1) Orange front; 2nd softest attachment at the rear (+2), where 0 is disconnected and +4 is stiffest setting
2) Blue front; +3 at rear
3) Wet - no front; 0 or +1 at rear
My startpoint will depend on the circuit. At Bedford I'd start stiff, as the track is smooth. At Combe, opposite. In context, when we raced at Cadwell at the weekend I did one race on 1) and one race on 2). Neither was really right, but I didn't get enough time in testing on Friday, 'cos of the rain, to realise this (At that point, I would have left the front on orange, stiffened the rear a little and reduced the rake, by lowering the rear a mm or 2).
BUT, TAKE NOTE - I'VE NEVER USED AO21s. And this would be a horrible car to drive on the road (too stiff, too low, would tramline and would constantly want to run me off the road - which is desirable on track, but less so on a country road).
Jez