Yes, that's something I've often wondered as well (why a LiIon can't cope with a standard charger, but doesn't mind getting a full 14+ volts from an alternator). There seem to be a couple of possible explanations that I can think of: A standard charger might decide that in order to get the battery up to (say) 13.5 volts, it should put 16v across the battery, which would be too high for LiIon. An alternator puts out rectified AC current. So although it might be supplying (say) 14.3v or so, it's not a constant 14.3, it actually varies between 0 and 14.3, and the battery can handle this much better than a pure DC 14.3v.I'm not totally convinced by either of these explanations, and would love someone who actually understands the issues to explain them.