I had a similar problem. I tracked it down to a slight leak in the hose joints - there was no residue visible on the pipes and they only leaked when hot and under pressure (i.e. engine running).
On topping up the tank (with the proper Red stuff) I noticed that the level in the EXPANSION tank moved up and down - the tank, if filled to the mark when cold, comes up to the cap when it is hot.
If you are filling the tank to the line when it is hot, then the tank looks almost empty when it cools. If you fill it beyond the mark, the coolant expands to the top of the tank and then any excess vents out of pressure cap, so some will appear to leak (it does, but it is meant to!).
I hope this makes sense - and helps!
Steve