So, just to close this one off. Having confirmed the battery & alternator were both good, I took the car back to Bristol Auto Electrical for them to diagnose the fault. Thankfully they did find and fix the issue. The problem was a faulty earth connection, possibly the one that goes to the chassis near the alternator. BAE said that they had carried out lots of voltage drop tests and resistance checks and noticed that when they simply put the car into gear, the charge level began to drop a little. So just that small engine movement was enough to trigger the poor earth connection. BAE's preferred fix was to introduce a new earth strap going from the battery earth to the starter motor. Job done, my temporary volt meter is now showing charging levels of around 14 volts, higher than I've ever seen! Whilst reading some of the content on here recently I noticed a post by somebody that said "90% of electrical issues on 7s were caused by poor earth connections". I'll bear that in mind for the future and try to improve my own diagnostic & multi-meter skills. Thanks again to all who've helped me with this :-)